When I first read this I was puzzled but now that i think about it, it makes sense. Playfield angle does play a part. Think of a Hot Wheels car on a loop track. When the car made it over the top of the loop they stayed on the track, but if they lost momentum they would drop like a rock when they got to the top of the loop.
So the ball spins along the outside edge. It loses momentum as it goes uphill to 12 o'clock. If it has enough momentum to get past 12 o'clock it picks up a little speed as it comes back down. Eventually the momentum is reduced until gravity takes over and the ball falls down into the hole. This spot will usually be right at the apex or 12 o'clock position.
It would be real hard for it to land in the bottom holes (especially 6 o'clock) because the ball will gain speed as it comes off the loop. The ball would need to have almost no momentum at all, because at the 6 o''clock position the ball would have to (for lack of a better word) fall up, as the holes on the bottom edge will be above the balls path.
This wouldn't be a factor if the roulette wheel were level, like in Vegas. This might be one of the cases were shiny and smooth are not what you want. If you had more friction from either the ball or the edge of the wheel you would probably get more random results.