Quoted from erichill:Obviously, I'd be foolish to think they'd accept liability if I hurt myself.
I too did a lot of research before diving into this and completely agree that the safest route would be to use a supplied air system instead of purification. But based on my research, talking to painters in town, and talking to the people at the shop, I was told that using an organic vapor filter in combination with a particulate filter provides adequate purification of isocyanates. The most important thing however is to observe the change out schedule for the filter cartridges and to keep them in an air tight container when not in use. Once they near end of life, they're no longer protecting you.
Digging through some old emails, here are some of the tech docs I found:
http://multimedia.3m.com/mws/media/603272O/respirator-selection-for-diisocyanates.pdf
http://www.grainger.com/content/qt-233-isocyanate
http://multimedia.3m.com/mws/media/777847O/isocyanates-3m-techupdate.pdf
Those references were very helpful and line up with my own research into the topic. The key point in the last reference is the protection used should reduce exposure from being above a safe level to something below the safe level. The OSHA practice of only recommending the equipment that reduces it the most is not entirely valid. In this case a full face pressure fed respirator is obviously better than a cartridge mask. It does not mean that the cartridge mask is inadequate, its just not as good.