My wife an I just got done watching the new Kurt Cobain documentary "montage of heck" and I was sitting there thinking about how Nevermind was such an impressive album. It's simple but brilliant, just a well written piece of art.
Here are some of my favorites (no particular order):
Beatles - Abby Road
Radiohead - OK Computer (Kid A is great as well)
Coltrane - Blue Train
Beck - Sea Change
Elton John - Madman Across the Water
Bela Fleck & the Flecktons - 1st Album
Pat Metheny - Imaginary Day
Nirvana - Nevermind
Rage against the Machine - 1st Album
NIN - Pretty Hate Machine
Pink Floyd - Dark Side of the Moon
Anyway, just first few that came to mind.