I just started buffing parts myself so I'm no expert. But I went with the hf buffing wheel. It was cheap and it does a nice job. I've been using a green compound I bought at hf and also trying the sample pack at sears. So far I've not noticed any difference in results.
The first parts I did, I didn't get a great mirror shine. But on the last few parts I've used a little more compound, and did multiple passes on the wheel now the parts end up looking great.
I've been buffing the brackets on the bottom of the playfield - flipper brackts, slings, and pops. And now after some trial and error I have a good feel for the process now. So my advice is just to practice and you'll get a feel for it.
For starting out I watched pinball mike d's monster bash video where he goes over his process for buffing. A much watch to get you going
Have fun with buffing - I know I am. I want to buff every metal part now. Its almost as addictive as pinside!