I wonder if the back of the cabinet has been sitting stored vertically, on a concrete floor. It may have sucked moisture for years, preventing your primer/paint to fully cure.
On my Xenon, I had a similar issue where the back of the cabinet had sucked so much water and moisture from sitting on the ground/concrete, that it was warped and chipping. The little plastic feet are useless when it comes to isolating the cabinet from the ground.
Yes, try to isolate with Kilz (only the back), let it dry and paint one coat of yellow. Then place the machine against the wall.
You will never look at it again.
Yves